Kinetic Observations in Menschutkin Reaction
نویسندگان
چکیده
منابع مشابه
Dramatic acceleration of the Menschutkin reaction and distortion of halide leaving-group order.
Compared to structurally related linear trialkylamines, a simple macrocyclic amine with an anion-binding cavity exhibits very large rate enhancements (>10(5)) for stoichiometric N-alkylation with primary alkyl, allyl, and benzyl halides in the weakly polar solvent CDCl3. There is also a major distortion of the halide leaving-group order. For example, with benzyl halides the relative leaving-gro...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1964
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.22.261